Magnalube-GX MSDS(English)

MATERIAL SAFETY DATA SHEETS
1. PRODUCT AND COMPANY IDENTIFICATION
Trade Name: Magnalube-GX
Product Description: Lubricating Grease
Product Numbers: MGX145, MGX1LB, MGX5LB, MGX35LB, MGX120LB, MG400LB
Product Use: Lubricating Grease
Manufacturer:
Magnalube, Inc.
PO Box 1250
Linden, NJ 07036
Tel: (718) 729-1000
Fax: (718) 729-2690
Emergency Telephone: Infotrac
U.S. and Canada: 1 (800) 535-5053
Outside the U.S. and Canada: 1 (352) 323-3500
Date of Last Issue: March 1st 2010
2. COMPOSITION AND INFORMATION ON INGREDIENTS
Ingredient Name: Highly Refined Mixture: Lubricating Oils, Petroleum, Base Oils
CAS No. WEIGHT
See full list below (***) 70-85 %
Ingredient Name: *OCTADECANOIC ACID, 12-HYDROXY-, MONOLITHIUM SALT
CAS No. WEIGHT
7620-77-1 7-13%
ACC26847
Ingredient Name: CARBONIC ACID CALCIUM SALT (COMMON NAME: CALCIUM CARBONATE)
CAS No. WEIGHT
471-34-1 3-7%
Ingredient Name: *PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYL ESTERS, *ZINC SALTS
CAS No. WEIGHT
68649-42-3 1-5%
Ingredient Name: *MOLYBDENUM SULFIDE (MoS2)
CAS No. WEIGHT
1317-33-5 1-5%
Ingredient Name: *ANTIMONY DIALKYLDITHIOCARBAMATE
CAS No. WEIGHT
(NJTSRN 800983-5015P OR CAS#15890-25-2) < 0-0.5 %
(***) The base oil for this product can be a mixture of any of the following: CAS 72623871; CAS 64741975;CAS 64742014; CAS 64742525; CAS 64741953; CAS 64742536; CAS 64741884; CAS 64742547; CAS 64742558; CAS 64742569; CAS 64742570; CAS 64741895; CAS 64741964;CAS 64742627; CAS 64742638; CAS 64742650; CAS 72623837; CAS 72623859; CAS 72623860.
The petroleum base oils contained in this product have been highly refined by a variety of processes including:
Solvent extraction, solvent dewaxing and hydrotreating to remove aromatics and improve performance characteristics.
Carcinogenicity: All petroleum base oils contained in this product meet the IP 346 criteria of less than 3 percent DMSO extractable PAH’s and are not considered carcinogens by IARC, NTP or OSHA.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: Exposure to vapors generated at high temperatures may cause respiratory irritation.
Carcinogenicity: IARC: Not listed as a Group 1, 2A, or 2B agent. OSHA: Not regulated. NTP: Not listed.
Eyes: May cause mild eye irritation.
Ingestion: May cause discomfort if swallowed.
Inhalation: Inhalation hazard at room temperature is unlikely due to the low volatility of this product. Heating can generate vapors that may cause respiratory irritation, nausea and headaches.
Sensitization: No known information.
Skin: Prolonged or repeated contact leads to drying of skin.
Teratogenicity: No known information.
HEALTH WARNINGS:

 

Eye Contact:Slightly irritating.
Ingestion: Can cause stomachache and vomiting.
Inhalation: Heating can generate vapors that may cause respiratory irritation, nausea and headaches. Inhalation hazard at room temperature is unlikely due to the low volatility of this product.
Skin Contact: Repeated or prolonged contact can result in drying of the skin.
Route of Entry: Inhalation. Skin and/or eye contact. Ingestion.
4. FIRST AID MEASURES
Eyes: Rinse with water. Contact physician if discomfort continues..
Ingestion: Get medical attention immediately! If vomiting occurs, lean forward to reduce the risk of aspiration.
Inhalation: Move the exposed person to fresh air at once. For breathing difficulties oxygen may be necessary.Get medical attention if any discomfort continues.
Skin: Remove contaminated clothing. Wash skin thoroughly with soap and water. Get medical attention if anydiscomfort continues.
INJECTION INJURY WARNING: If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury
5. FIRE FIGHTING MEASURES
Flash Point: (°C) 210 (410°F) Cd OC (Cleveland open cup).
Flammability Limit - Lower(%): N/D
Flammability Limit - Upper(%): N/D
Extinguishing Media: Water spray, fog or mist. Foam. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc.
Special Fire Fighting Procedures: Use water to keep fire exposed containers cool and disperse vapors. Water
spray may be used to flush spills away from exposures and dilute spills to non-flammable mixtures. Avoid water in straight hose stream; will scatter and spread fire. Keep run-off water out of sewers and water sources. Dike for water control.
Unusual Fire & Explosion Hazards: Volume and pressure increases strongly when heated. Risk of container explosion in fire.
Hazardous Combustion Products: Acrid smoke/fumes. Oxides of: Carbon. Nitrogen. Sulfur.
Protective Measures In Case of Fire: Self-contained breathing equipment and chemical resistant clothing recommended.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Minimize skin contact.
Precautions To Protect The Environment: Keep product out of sewers and watercourses by diking or impounding.
Advise authorities if product has entered or may enter sewers, watercourses or extensive land areas. Assure conformity with applicable government regulations.
Spill Clean-Up Procedures: Provide good ventilation. Use appropriate protective clothing. Carefully collect spilled material in closed containers and leave for disposal according to local regulations. Do not let washing down water contaminate ponds or waterways. Rinse area with water.
7. HANDLING AND STORAGE
Handling Precautions: Keep away from heat, sparks and open flame. Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is above accepted level. Containers should be kept tightly closed. Avoid spilling, skin and eye contact. Eye wash and emergency shower must be available at the work place.
Storage Precautions: Keep away from heat, sparks and open flame. Store separated from: Acids. Oxidizing materials.
Storage Criteria: Chemical storage.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Component: Lubricating Oils, Petroleum, Base Oils, Highly Refined Mixture (***)
STD TWA STEL
OSHA 5 mg/m3 as oil mist
ACGIH 5 mg/m3 as oil mist 10 mg/m3 as oil mist
Component: CARBONIC ACID CALCIUM SALT (COMMON NAME: CALCIUM CARBONATE)
STD TWA STEL
OSHA 10 mg/m3 (total) 5 mg/m3 (resp)
ACGIH 10 mg/m3
Component: MOLYBDENUM SULFIDE (MoS2)
STD TWA STEL
OSHA N/E
ACGIH 3 mg/m3 (resp) as Mo 10 mg/m3 (ihl) as Mo
Component: ANTIMONY DIALKYLDITHIOCARBAMATE (NJTSRN 800983-5015P OR CAS# 15890-25-2)
STD TWA STEL
OSHA 0.5 mg/m3 as Sb
ACGIH 0.5 mg/m3 as Sb
PROTECTIVE EQUIPMENT:
Gloves and protective eyewear recommended.
Eye Protection: Use eye protection.
Engineering Controls: Use engineering controls to reduce air contamination to permissible exposure level.
Hygienic Work Practices: Wash at the end of each work shift and before eating, smoking and using the toilet.
Protective Clothing: Wear appropriate clothing to prevent repeated or prolonged skin contact
Protective Gloves: Chemical resistant gloves required for prolonged or repeated contact. Use protective glovesmade of: Neoprene, nitrile, polyethylene or PVC.
Respirators: No specific recommendation made, but respiratory protection may still be required under exceptional
circumstances when excessive air contamination exists.
Ventilation: No specific ventilation requirements noted, but forced ventilation may still be required if air contamination exceeds acceptable level.
9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance/Physical State: Grease.
Color: Grey.
Odor: Mild (or faint).
Solubility Description: Insoluble in water.
Density: 0.90 Temperature: (°C) 15.6 (60°F)
Vapor Density (air=1): > 5
Vapor Pressure: < 0.1 mmHg Temperature:(°C) 20 (68°F)
Evaporation: Rate <1 Reference: BuAc=1
pH-Value, Conc. Solution: N/A

10. STABILITY AND REACTIVITY

Stability: Normally stable.
Conditions To Avoid: Avoid contact with acids and oxidizing substances.
Hazardous Polymerization: Will not polymerize.
Hazardous Decomposition Products: Oxides of: Carbon. Phosphorus. Sulfur.

11. TOXICOLOGICAL INFORMATION

Toxicological Information: No experimental toxicological data on the preparation as such is available.


COMPONENT: Lubricating Oils, Petroleum, Base Oils, Highly Refined Mixture (***)
Toxicological Data: Carcinogenicity. IP 346 <3%
Toxic Dose - LD50: > 5000 mg/kg (oral rat)
Toxic Dose - LD50 Skin: > 2000 mg/kg (skn rbt)
Toxic Conc. - LC50: No Information Available (NIA).

COMPONENT:OCTADECANOIC ACID, 12-HYDROXY-, MONOLITHIUM SALT
Toxic Dose - LD 50: No Information Available (NIA).
Toxic Conc. - LC 50: No Information Available (NIA).

COMPONENT:PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTS
Toxic Dose - LD 50:4739 mg/kg (oral rat).
Toxic Conc. - LC 50SKIN: > 2000 mg/kg (skn rbt)

12. ECOLOGICAL INFORMATION

Ecological Information: No data on possible environmental effects have been found.


COMPONENT: Lubricating Oils, Petroleum, Base Oils, Highly Refined Mixture (***)
COMPONENT:PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTS

Ecotoxicological Data:WGK 2

13. DISPOSAL CONSIDERATIONS

Disposal Methods: Spilled material, unused contents and empty containers must be disposed of in accordance with local, state and federal regulations.

14. TRANSPORT INFORMATION

DOT Hazard Class: Not regulated.
Reportable Quantity (RQ): No.
Sea Transport Notes: Not regulated per IMDG.
Air Transport Notes: Not regulated per IATA.

15. REGULATORY INFORMATION
US FEDERAL REGULATIONS:
COMPONENT: Lubricating Oils, Petroleum, Base Oils, Highly Refined Mixture (***)
SARA 302 CERCLA SARA 313
No No No
COMPONENT: OCTADECANOIC ACID, 12-HYDROXY-, MONOLITHIUM SALT
SARA 302 CERCLA SARA 313
No No No
COMPONENT:CARBONIC ACID CALCIUM SALT (COMMON NAME: CALCIUM CARBONATE)
SARA 302 CERCLA SARA 313
No No No
COMPONENT: PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTS
SARA 302 CERCLA SARA 313
No No No
COMPONENT: MOLYBDENUM SULFIDE (MoS2)
SARA 302 CERCLA SARA 313
No ***** N982 - Zn
COMPONENT: ANTIMONY DIALKYLDITHIOCARBAMATE (NJTSRN 800983-5015P OR CAS# 15890-25-2)
SARA 302 CERCLA SARA 313
No ***** N010 – Sb
Regulatory Status: ***** Indicates that no RQ is assigned to this generic or broad class, although the class is a CERCLA hazardous substance. See 50 Federal Register 13456 (April 4, 1985). Values in Section 313 column represent Category Codes for reporting under Section 313.

CLEAN AIR ACT:
SARA Hazard Categories: Acute Chronic
US STATE REGULATIONS:

COMPONENT: Lubricating Oils, Petroleum, Base Oils, Highly Refined Mixture (***)
CA MA FL MN NJ PA RI
Yes Yes
COMPONENT: PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTS
CA MA FL MN NJ PA RI
No Yes Yes EH
COMPONENT: Lubricating Oils, Petroleum, Base Oils, Highly Refined Mixture (***)
CA MA FL MN NJ PA RI
Yes
COMPONENT: Organic Polyurea Thickener (TSCA Accession #26847)
CA MA FL MN NJ PA RI
No Yes EH

Workplace Hazardous Materials Information System - WHMIS: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

LABEL(S) FOR SUPPLY:

CONTROLLED PRODUCT CLASSIFICATION:D2B - Irritating and/or Chronically Toxic Materials.

Risk Phrases : R-20/22 Harmful by inhalation and if swallowed.
R-36/37/38 Irritating to eyes, respiratory system and skin.
R-51/53 Toxic to aquatic organisms, may cause long-term adverse effect in the aquatic environment

GLOBAL INVENTORIES:

COMPONENT: Lubricating Oils, Petroleum, Base Oils, Highly Refined Mixture (***)

CAN US EU AUS JAP KOR PHLP CHN
DSL Yes EINECS Yes Yes Yes Yes Yes
COMPONENT: OCTADECANOIC ACID, 12-HYDROXY-, MONOLITHIUM SALT
CAN US EU AUS JAP KOR PHLP CHN
DSL Yes EINECS No 2-1416 No No Yes
COMPONENT: CARBONIC ACID CALCIUM SALT (COMMON NAME: CALCIUM CARBONATE)
CAN US EU AUS JAP KOR PHLP CHN
Yes Yes N/A N/A 1-122 Yes Yes Yes
COMPONENT: PHOSPHORODITHIOIC ACID, O, O-DI-C1-14-ALKYL ESTERS, ZINC SALTS
CAN US EU AUS JAP KOR PHLP CHN
DSL Yes EINECS Yes Yes Yes Yes Yes
COMPONENT: MOLYBDENUM SULFIDE (MoS2)
CAN US EU AUS JAP KOR PHLP CHN
DSL Yes EINECS No PRTR1 No No Yes
COMPONENT: ANTIMONY DIALKYLDITHIOCARBAMATE (NJTSRN 800983-5015P OR CAS# 15890-25-2)
CAN US EU AUS JAP KOR PHLP CHN
NPRI Yes EINECS Yes Yes Yes Yes Yes

CANADA (CEPA): All components of this product comply with new substance notification requirements under the Canadian Environmental Protection Act (CEPA).
USA (TSCA): All components in this product are listed on the US Toxic Substances Control Act (TSCA) Inventory or are exempt from TSCA Inventory requirements.
Canada (DSL): All components in this product are listed on the Canada Domestic Substances List (DSL) or are exempt from DSL requirements
Europe (EINECS/ELINCS/NLP): All components in this product are listed on the European Inventory of New and Existing Chemical Substances (EINECS), the European List of Notified Chemical Substances (ELINCS), or the No Longer Polymers (NLP) list, or are exempt from EU listing requirements
Phillipines (PICCS): This product contains one or more components that are NOT LISTED on the Philippines Inventory of Chemicals and Chemical Substances (PICCS) and are NOT EXEMPT from PICCS requirements.
Australia (AICS): This product contains one or more components that are NOT LISTED on the Australian Inventory of Chemical Substances (AICS) and are NOT EXEMPT from AICS requirements.
China (IECS): All components in this product are listed on the China Inventory of Existing Chemical Substances (IECS) or are exempt from IECS requirements.

16. OTHER INFORMATION

NFPA-HMIS HAZARD RATING:


Health: Irritation, minor residual injury (1) - HMIS/NFPA
Flammability: Burns only if pre-heated (1) - HMIS/NFPA
Reactivity: Normally Stable (0) - HMIS/NFPA
NPCA HMIS Hazard Index: Slight; Slightly Toxic - May cause slight irritation (1).
Personal Protection Index: B - Safety Eyewear and Gloves
NPCA HMIS Flammability Index: Burns only if pre-heated (1).
Tariff Code (Schedule B): 2710.19.3750 Lubricating greases, with or without additives.

REVISION COMMENTS:


Prepared By: Compliance
Date: March 29th 2010


Disclaimer: While the information and recommendations set forth herein are believed to be accurate as of th date there of, the company makes no warranty with respect thereto and disclaims all liability from reliance therein.